聚丙烯(xi)(xi)酰(xian)(xian)胺(an)(an)因(yin)其分(fen)子(zi)鏈長能(neng)吸附(fu)雜(za)質,處理(li)污(wu)(wu)水(shui)效(xiao)果(guo)好而得(de)名(ming),其可以分(fen)為陰離(li)子(zi)、陽離(li)子(zi)和非離(li)子(zi)聚丙烯(xi)(xi)酰(xian)(xian)胺(an)(an),聚丙烯(xi)(xi)酰(xian)(xian)胺(an)(an)的(de)(de)(de)(de)特點是粘稠(chou),它固有的(de)(de)(de)(de)特點是其不(bu)僅能(neng)用在(zai)污(wu)(wu)水(shui)處理(li)中(zhong),還(huan)可作為增稠(chou)劑(ji)、潤滑(hua)劑(ji)、保(bao)水(shui)劑(ji)等應用于不(bu)同行業。所(suo)以,再污(wu)(wu)水(shui)處理(li)中(zhong),聚丙烯(xi)(xi)酰(xian)(xian)胺(an)(an)的(de)(de)(de)(de)粘度(du)還(huan)是肉(rou)眼(yan)可見的(de)(de)(de)(de)一項比較重要的(de)(de)(de)(de)指標,那么如何提高聚丙烯(xi)(xi)酰(xian)(xian)胺(an)(an)粘度(du),防止(zhi)其降(jiang)解(jie)呢?
聚(ju)(ju)(ju)丙(bing)(bing)(bing)(bing)(bing)烯(xi)(xi)酰(xian)(xian)(xian)胺(an)(an)型號眾多(duo),相對(dui)來(lai)說,陽離(li)子(zi)處理(li)污水范圍相對(dui)廣,價格高,聚(ju)(ju)(ju)丙(bing)(bing)(bing)(bing)(bing)烯(xi)(xi)酰(xian)(xian)(xian)胺(an)(an)粘度(du)下降的(de)(de)原因和存放(fang)時間有很大(da)的(de)(de)關系(xi),一般而言,陰離(li)子(zi)型聚(ju)(ju)(ju)丙(bing)(bing)(bing)(bing)(bing)烯(xi)(xi)酰(xian)(xian)(xian)胺(an)(an)溶(rong)液(ye)可以存放(fang)3天(tian),陽離(li)子(zi)聚(ju)(ju)(ju)丙(bing)(bing)(bing)(bing)(bing)烯(xi)(xi)酰(xian)(xian)(xian)胺(an)(an)溶(rong)液(ye)僅可以存放(fang)24小(xiao)時。這是由于酰(xian)(xian)(xian)胺(an)(an)基(ji)團水解,羥基(ji)含(han)量(liang)(liang)增加的(de)(de)原因。特(te)別是含(han)有陽離(li)子(zi)基(ji)的(de)(de)影響(xiang)更(geng)(geng)為明顯,酰(xian)(xian)(xian)胺(an)(an)基(ji)團脫去NH3生成(cheng)酰(xian)(xian)(xian)亞胺(an)(an)基(ji)團是分子(zi)鏈剛性增加所致。聚(ju)(ju)(ju)丙(bing)(bing)(bing)(bing)(bing)烯(xi)(xi)酰(xian)(xian)(xian)胺(an)(an)溶(rong)液(ye)隨著儲放(fang)時間增加,降解的(de)(de)越(yue)多(duo),粘度(du)也越(yue)低,絮凝效果也越(yue)差。特(te)別是在儲存條(tiao)件比較(jiao)差的(de)(de)情況(kuang)下溶(rong)液(ye)粘度(du)的(de)(de)變化(hua)會(hui)更(geng)(geng)大(da)更(geng)(geng)明顯,所以,大(da)家可以通(tong)過改善存放(fang)條(tiao)件來(lai)發盡量(liang)(liang)減少粘度(du)變化(hua)的(de)(de)幅度(du)!
聚丙烯酰胺粘(zhan)度下降的原因和溫度、雜質(zhi)、礦化度、分子量都有關系
1、溫度對聚丙(bing)烯酰(xian)胺粘度的(de)影響
當溫(wen)度(du)達到80 - 90℃時(shi),1800萬的分(fen)(fen)(fen)子(zi)量會在2-4小時(shi)內(nei)降(jiang)解到500萬左右,并且降(jiang)解會隨著(zhu)溫(wen)度(du)的升高(gao)(gao)(gao)而變得越來越快。在25℃的室溫(wen)下性能穩定。溫(wen)度(du)是(shi)分(fen)(fen)(fen)子(zi)無(wu)規則(ze)熱運動(dong)激烈程度(du)的反映,分(fen)(fen)(fen)子(zi)的運動(dong)須克服分(fen)(fen)(fen)子(zi)間(jian)的相互作(zuo)用(yong)力(li),而分(fen)(fen)(fen)子(zi)間(jian)的相互作(zuo)用(yong),如分(fen)(fen)(fen)子(zi)間(jian)氫(qing)鍵、內(nei)摩擦、擴(kuo)散、分(fen)(fen)(fen)子(zi)鏈取向、纏(chan)結等,直接影(ying)響(xiang)粘度(du)的大小,故高(gao)(gao)(gao)聚物(wu)溶(rong)液的粘度(du)會隨溫(wen)度(du)發生變化。溫(wen)度(du)改變對高(gao)(gao)(gao)聚物(wu)溶(rong)液粘度(du)的影(ying)響(xiang)是(shi)顯著(zhu)的。聚丙烯酰(xian)胺溶(rong)液的粘度(du)隨溫(wen)度(du)的升高(gao)(gao)(gao)而降(jiang)低(di),其原因(yin)是(shi)高(gao)(gao)(gao)分(fen)(fen)(fen)子(zi)溶(rong)液的分(fen)(fen)(fen)散相粒子(zi)彼(bi)此糾纏(chan)形(xing)成網狀結構的聚合(he)體,溫(wen)度(du)越高(gao)(gao)(gao)時(shi),網狀結構越容易破壞,故其粘度(du)下降(jiang)。
2、雜質對聚丙烯酰胺粘度(du)的影響
雜(za)質(zhi)的影(ying)(ying)響是(shi)溶解聚丙(bing)烯酰胺干粉的時(shi)候,要使(shi)用(yong)(yong)中性水(shui),因(yin)為水(shui)的硬度大,或者(zhe)含有雜(za)質(zhi),都會影(ying)(ying)響聚丙(bing)烯酰胺的粘度和(he)使(shi)用(yong)(yong)效果。
3、礦(kuang)化度對聚丙烯酰胺粘(zhan)度的(de)影響
聚(ju)丙烯酰(xian)胺(an)分(fen)子鏈中(zhong)陽離(li)子基團(tuan)相(xiang)對于陰離(li)子基團(tuan)數(shu)目較多,凈(jing)電(dian)荷較多,根據(ju)相(xiang)似相(xiang)溶(rong)原理,聚(ju)合(he)物(wu)水溶(rong)性(xing)較好(hao),特性(xing)黏度較大;隨著礦物(wu)質含(han)量的增(zeng)加(jia),正(zheng)(zheng)的靜(jing)電(dian)荷部(bu)分(fen)被陰離(li)子包圍(wei)形(xing)成離(li)子氛,從(cong)而與(yu)周圍(wei)正(zheng)(zheng)的靜(jing)電(dian)荷結合(he),黏度減(jian)小(xiao)(xiao);礦物(wu)質濃(nong)度繼續增(zeng)加(jia),正(zheng)(zheng)、負離(li)子基團(tuan)形(xing)成分(fen)子內或分(fen)子間氫鍵的締(di)合(he)作(zuo)用(導致聚(ju)合(he)物(wu)在水中(zhong)的溶(rong)解(jie)性(xing)下(xia)降),同(tong)時(shi)加(jia)入的鹽(yan)離(li)子通(tong)過(guo)屏蔽正(zheng)(zheng)、負電(dian)荷,拆散正(zheng)(zheng)、負離(li)子間締(di)合(he)而使(shi)已形(xing)成的鹽(yan)鍵受到(dao)破壞(huai)(導致聚(ju)合(he)物(wu)在水中(zhong)的溶(rong)解(jie)性(xing)增(zeng)大),這兩(liang)種作(zuo)用相(xiang)互競爭,使(shi)得聚(ju)合(he)物(wu)溶(rong)液在較高(gao)的鹽(yan)濃(nong)度(>0.06 mol/L)下(xia)粘(zhan)度保持較小(xiao)(xiao)。
4、分子量對(dui)聚丙烯酰胺粘(zhan)度的影響
聚(ju)丙烯酰胺(an)溶(rong)(rong)(rong)液(ye)(ye)的(de)粘度(du)隨(sui)高(gao)聚(ju)物(wu)(wu)分子(zi)(zi)量(liang)的(de)增(zeng)大而增(zeng)大,這是由于高(gao)分子(zi)(zi)溶(rong)(rong)(rong)液(ye)(ye)的(de)粘度(du)由分子(zi)(zi)運動時(shi)(shi)分子(zi)(zi)間(jian)的(de)相(xiang)互作用產(chan)生。當聚(ju)合(he)(he)物(wu)(wu)相(xiang)對分子(zi)(zi)質(zhi)量(liang)約為106時(shi)(shi),高(gao)分子(zi)(zi)線團(tuan)開始相(xiang)互滲透,足以(yi)影(ying)響對光(guang)的(de)散射。含(han)量(liang)稍(shao)高(gao)時(shi)(shi)機(ji)械纏結足以(yi)影(ying)響粘度(du)。含(han)量(liang)相(xiang)當低時(shi)(shi),聚(ju)合(he)(he)物(wu)(wu)溶(rong)(rong)(rong)液(ye)(ye)可視為網(wang)狀(zhuang)結構(gou),鏈(lian)間(jian)機(ji)械纏結和氫(qing)鍵共同形成(cheng)網(wang)的(de)節點。含(han)量(liang)較高(gao)時(shi)(shi),溶(rong)(rong)(rong)液(ye)(ye)含(han)有(you)許多鏈(lian)-鏈(lian)接觸點,使(shi)高(gao)聚(ju)物(wu)(wu)溶(rong)(rong)(rong)液(ye)(ye)呈凝(ning)膠狀(zhuang)。因此,高(gao)聚(ju)物(wu)(wu)相(xiang)對分子(zi)(zi)質(zhi)量(liang)越大,分子(zi)(zi)間(jian)越易形成(cheng)鏈(lian)纏結,溶(rong)(rong)(rong)液(ye)(ye)的(de)粘度(du)越大。
了解(jie)了這些易(yi)造成聚(ju)丙(bing)(bing)烯(xi)酰(xian)胺粘度(du)降低(di)的原(yuan)因后我(wo)們(men)(men)要(yao)盡(jin)量去避免(mian),因為粘度(du)的降低(di)勢(shi)必(bi)會影響聚(ju)丙(bing)(bing)烯(xi)酰(xian)胺的使(shi)(shi)用效果。更多(duo)關于(yu)聚(ju)丙(bing)(bing)烯(xi)酰(xian)胺的使(shi)(shi)用問題歡迎致電河南泰航凈水材料(liao)有限公司技術人員(yuan),我(wo)們(men)(men)將竭(jie)誠為您服務(wu)!