固(gu)體聚丙烯酰胺(an)(acylamide)在使用之前,一般都要將其固(gu)體溶合(he)成溶液(ye),然后投加使用。聚丙烯酰胺(an)廠家聚丙烯酰胺(an)作(zuo)為(wei)潤滑劑(ji)、懸浮劑(ji)、粘土穩定劑(ji)、驅油(you)(you)(you)(you)劑(ji)、降失水劑(ji)和增(zeng)稠劑(ji),在鉆井、酸化(hua)、壓裂、堵水、固(gu)井及二次采(cai)(cai)油(you)(you)(you)(you)、三次采(cai)(cai)油(you)(you)(you)(you)中得到了(le)廣(guang)泛應用,是一種極(ji)為(wei)重要的油(you)(you)(you)(you)田(tian)化(hua)學(xue)品。
聚(ju)(ju)丙(bing)(bing)烯酰胺(an)(an)(an)(an)(an)聚(ju)(ju)丙(bing)(bing)烯酰胺(an)(an)(an)(an)(an)按其結構(gou)又(you)可(ke)(ke)分為非(fei)離(li)(li)子(zi)(zi)型(xing)、陰離(li)(li)子(zi)(zi)型(xing)和陽(yang)離(li)(li)子(zi)(zi)型(xing)。陰離(li)(li)子(zi)(zi)型(xing)多為PAM 的水解體(ti)(HPAM)。聚(ju)(ju)丙(bing)(bing)烯酰胺(an)(an)(an)(an)(an)的主鏈(lian)上帶(dai)有大量(liang)的酰胺(an)(an)(an)(an)(an)基,化(hua)學活性(xing)很(hen)高,可(ke)(ke)以改(gai)性(xing)制取(qu)許多聚(ju)(ju)丙(bing)(bing)烯酰胺(an)(an)(an)(an)(an)的衍生物,產品(pin)(pin)已(yi)廣泛應用于造紙、選(xuan)礦(kuang)、采油、冶金、建材、污水處理等行(xing)業。聚(ju)(ju)丙(bing)(bing)烯酰胺(an)(an)(an)(an)(an)廠家聚(ju)(ju)丙(bing)(bing)烯酰胺(an)(an)(an)(an)(an)為白(bai)(bai)色(se)粉末或者小顆(ke)粒狀物,密度(du)(du)為1.32g/cm3(23度(du)(du)),玻璃(li)化(hua)溫度(du)(du)為188度(du)(du),軟化(hua)溫度(du)(du)近于210度(du)(du),一(yi)般(ban)方法干燥(zao)時含有少量(liang)的水,干時又(you)會很(hen)快(kuai)從環境中(zhong)吸取(qu)水分,用冷凍干燥(zao)法分離(li)(li)的均聚(ju)(ju)物是(shi)白(bai)(bai)色(se)松軟的非(fei)結晶固(gu)(gu)體(ti),但是(shi)當從溶液中(zhong)沉淀(dian)并干燥(zao)后則為玻璃(li)狀部分透明的固(gu)(gu)體(ti),完全干燥(zao)的聚(ju)(ju)丙(bing)(bing)烯酰胺(an)(an)(an)(an)(an)PAM是(shi)脆(cui)性(xing)的白(bai)(bai)色(se)固(gu)(gu)體(ti),商品(pin)(pin)聚(ju)(ju)丙(bing)(bing)烯酰胺(an)(an)(an)(an)(an)干燥(zao)通常(chang)是(shi)在適度(du)(du)的條件下干燥(zao)的,一(yi)般(ban)含水量(liang)為5%~15%,澆鑄在玻璃(li)板上制備的高分子(zi)(zi)膜,則是(shi)透明、堅硬、易碎的固(gu)(gu)體(ti)。聚(ju)(ju)丙(bing)(bing)烯酰胺(an)(an)(an)(an)(an)聚(ju)(ju)丙(bing)(bing)烯酰胺(an)(an)(an)(an)(an)是(shi)一(yi)種(zhong)線型(xing)高分子(zi)(zi)聚(ju)(ju)合物,產品(pin)(pin)主要分為干粉和膠體(ti)兩種(zhong)形式。
按其平均分(fen)子(zi)(zi)量(liang)(liang)可分(fen)為低分(fen)子(zi)(zi)量(liang)(liang)(<100 萬)、中分(fen)子(zi)(zi)量(liang)(liang)(200~400 萬)和高(gao)(gao)(gao)(gao)分(fen)子(zi)(zi)量(liang)(liang)(>700萬)三類。現(xian)使用(yong)聚(ju)丙烯(xi)酰(xian)(xian)胺(an)(an)用(yong)于污泥污水處(chu)理(chǔ lǐ)行業比較(jiao)(jiao),當天配(pei)制好的 溶(rong)(rong)液(ye)(ye)當天使用(yong)效果很理想(xiang),但是(shi)(shi)(shi)放置一(yi)段(duan)時間過后,溶(rong)(rong)液(ye)(ye)粘(zhan)(zhan)度明顯(xian)下降(descend),效果也不好。那(nei)么主要是(shi)(shi)(shi)由哪些(xie)因素(factor)引起的 呢? 一(yi)般分(fen)子(zi)(zi)量(liang)(liang)越高(gao)(gao)(gao)(gao)的 聚(ju)丙烯(xi)酰(xian)(xian)胺(an)(an)的 溶(rong)(rong)液(ye)(ye)粘(zhan)(zhan)度越大(da),這是(shi)(shi)(shi)因為聚(ju)丙烯(xi)酰(xian)(xian)胺(an)(an)大(da)分(fen)子(zi)(zi)是(shi)(shi)(shi)細而長的 鏈狀體(ti),在溶(rong)(rong)液(ye)(ye)中運動的 阻(zu)力很大(da)。粘(zhan)(zhan)度的 實質是(shi)(shi)(shi)反映溶(rong)(rong)液(ye)(ye)內(nei)磨擦力的 大(da)小,亦稱為內(nei)磨擦系數(shu)。各種(zhong)高(gao)(gao)(gao)(gao)分(fen)子(zi)(zi)有(you)機(ji)物(wu)(wu)的 溶(rong)(rong)液(ye)(ye)的 粘(zhan)(zhan)度都比較(jiao)(jiao)高(gao)(gao)(gao)(gao),并隨分(fen)子(zi)(zi)量(liang)(liang)升(sheng)高(gao)(gao)(gao)(gao)而增大(da)。測定(ding)高(gao)(gao)(gao)(gao)分(fen)子(zi)(zi)有(you)機(ji)物(wu)(wu)分(fen)子(zi)(zi)量(liang)(liang)的 一(yi)種(zhong)方(fang)法,測定(ding)一(yi)定(ding)濃度溶(rong)(rong)液(ye)(ye)在一(yi)定(ding)條件下的 粘(zhan)(zhan)度,再按一(yi)定(ding)的 公式計算其分(fen)子(zi)(zi)量(liang)(liang),稱為 ;推定(ding)分(fen)子(zi)(zi)量(liang)(liang) ;。
而(er)聚丙(bing)烯(xi)(xi)酰胺(an)(an)(an)溶液(ye)的(de) 特性(xing)(xing)(xing)粘度(du) [η] 與其分子量m 之間(jian)有(you)(you)如下的(de) 指(zhi)數(shu)函數(shu)關系(xi) : [η] = 3。73 × 10-4 × m 0.66 經(jing)驗(yan)(experience)表明(ming),聚丙(bing)烯(xi)(xi)酰胺(an)(an)(an)的(de) 絮凝性(xing)(xing)(xing)能(neng)與它的(de) 溶液(ye)粘度(du)有(you)(you)直接的(de) 關系(xi),粘度(du)越(yue)高者性(xing)(xing)(xing)能(neng)越(yue)好,說分子量越(yue)高的(de) 聚丙(bing)烯(xi)(xi)酰胺(an)(an)(an)產品性(xing)(xing)(xing)能(neng)越(yue)優;如果它的(de) 粘度(du)受到某些因(yin)素(su)的(de) 影響而(er)降(jiang)低(reduce),其絮凝性(xing)(xing)(xing)能(neng)必(bi)然(ran)下降(jiang)。